Mono- and bilayer equilibria of stearate self-assembly formed in hydrotalcite interlayers by changing the intercalation temperature

被引：50

作者：

Kanoh, T ^{[1
]}

Shichi, T ^{[1
]}

Takagi, K ^{[1
]}

机构：

[1] Nagoya Univ, Fac Engn, Dept Crystalline Mat Sci, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 02期

关键词：

D O I：

10.1246/cl.1999.117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of sodium stearate and its homologs (>C-12) in hydrotalcite (LDH) interlayers was found to change reversibly between mono- and bilayer structures with a ratio changing continuously within a range of 70 degrees C and 5 degrees C in stoichiometric intercalations in aqueous dispersion. The bilayer structure was more stable: than the monolayer, judging from the fact that bilayer aggregations were formed even in high temperatures with the addition of excess amounts of guest stearates over the anion exchange capacity (AEC). Hydrophobic interaction was determined to be the key factor for the formation of a bilayer assembly.

引用

页码：117 / 118

页数：2

共 11 条

[1] FATTY-ACIDS IN LAYERED METAL-HYDROXIDES - MEMBRANE-LIKE STRUCTURE AND DYNAMICS [J].

BORJA, M ;

DUTTA, PK .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (13) :5434-5444

[2] 4-NITROHIPPURIC ACID IN LAYERED LITHIUM ALUMINATES - ONSET OF NONLINEAR OPTICAL-PROPERTIES [J].

COOPER, S ;

DUTTA, PK .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (01) :114-118

[3] Formation of second-stage intermediates in anion-exchange intercalation reactions of the layered double hydroxide [LiAl2(OH)6]Cl•H2O as observed by time-resolved, in situ X-ray diffraction [J].

Fogg, AM ;

Dunn, JS ;

O'Hare, D .

CHEMISTRY OF MATERIALS, 1998, 10 (01) :356-360

[4] PACKING DENSITY OF ORGANYLDIMETHYLSILOXY-COVERED SILICA-GEL AND HYDROLYTIC STABILITY OF THE COATING [J].

FOTI, G ;

BELVITO, ML ;

KOVATS, ES .

JOURNAL OF CHROMATOGRAPHY, 1988, 440 :315-322

[5]

Grim R.E., 1953, SOIL SCI, V76, P317

[6] KINK-BLOCK AND GAUCHE-BLOCK STRUCTURES OF BIMOLECULAR FILMS [J].

LAGALY, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (10) :575-586

[7]

MIYATA S, 1983, GYPSUM LIME, V187, P47

[8] Incorporation of poly(acrylic acid), poly(vinylsulfonate) and poly(styrenesulfonate) within layered double hydroxides [J].

Oriakhi, CO ;

Farr, IV ;

Lerner, MM .

JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (01) :103-107

[9] CONTROLLED PHOTOCYCLOADDITION OF UNSATURATED CARBOXYLATES INTERCALATED IN HYDROTALCITE CLAY INTERLAYERS [J].

TAKAGI, K ;

SHICHI, T ;

USAMI, H ;

SAWAKI, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) :4339-4344

[10] SPATIALLY CONTROLLED PHOTOCYCLOADDITION OF A CLAY-INTERCALATED STILBAZOLIUM CATION [J].

TAKAGI, K ;

USAMI, H ;

FUKAYA, H ;

SAWAKI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (16) :1174-1175

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