Recent excursions to the borderlands between the realms of concerted and stepwise: carbocation cascades in natural products biosynthesis

被引：126

作者：

Tantillo, Dean J. ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2008年 / 21卷 / 7-8期

关键词：

carbocation; concerted; synchronicity; terpene;

D O I：

10.1002/poc.1320

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent theoretical studies on concerted carbocation rearrangements that involve multiple asynchronous chemical events are described. The relevance of such rearrangements to natural products biosynthesis is highlighted. Copyright (c) 2008 John Wiley & Sons, Ltd.

引用

收藏

页码：561 / 570

页数：10

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