A [2]rotaxane capped by a cyclodextrin and a guest: Formation of supramolecular [2]rotaxane polymer

被引：96

作者：

Miyauchi, M

Hoshino, T

Yamaguchi, H

Kamitori, S

Harada, A

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 5600043, Japan

[2] Kagawa Univ, Ctr Informat Technol, Kita Ku, Miki, Kagawa 7610793, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 07期

关键词：

D O I：

10.1021/ja042840+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A [2]rotaxane capped by a β-cyclodextrin and a 2,4,6-trinitrophenyl group has been prepared by dissolving 6-aminocinnamoyl β-cyclodextrin in water with 1-adamantane carboxylic acid and complexation with α-cyclodextrin followed by the reaction with 2,4,6-trinitrobenzene sulfonic acid sodium salt. The [2]rotaxane has been found to form supramolecular polymers by host-guest interactions. Copyright © 2005 American Chemical Society.

引用

页码：2034 / 2035

页数：2

共 22 条

[1] Interlocked and intertwined structures and superstructures [J].