Bis[(mu-chloro)copper(II)]amethyrin: A bimetallic copper(II) complex of an expanded porphyrin

被引：72

作者：

Weghorn, SJ

Sessler, JL

Lynch, V

Baumann, TF

Sibert, JW

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

[2] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 05期

关键词：

D O I：

10.1021/ic9509692

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of a bis-copper(Il) complex of an expanded porphyrin is described. A single-crystal X-ray structural analysis of this complex showed the two metal centers to lie within the mean plane of the macrocycle with a rather short interatomic distance of 2.761(1) Angstrom. The two metal centers are formally in the +2 oxidation state and are weakly antiferromagnetically coupled. The overall complex is thus dianionic.

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页码：1089 / &

页数：3

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