A new method for assessing the thermal stability of semibatch processes based on lyapunov exponents

被引:30
作者
Alos, MA
Strozzi, F
Zaldivar, JM
机构
[1] Jt. Res. Ctr. Commn. Europ. Comm., Institute for Safety Technology, Process Engineering Division, TP 680
关键词
D O I
10.1016/0009-2509(96)00202-3
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Thermally safe operation of a SBR implies that conditions leading to a large accumulation of unconverted reactants are avoided. In this work a new method for assessing the thermal stability of semibatch processes is presented. The thermal runaway region is characterised as a function of the design parameters using a criterion based on the Lyapunov exponents. The results are in good agreement with existing methods. The advantages of this method are its simplicity and flexibility since it can be applied to complex systems without previous particular definitions.
引用
收藏
页码:3089 / 3094
页数:6
相关论文
共 8 条
[1]  
ALOS MA, 1995, IN PRESS
[2]  
BARTON JA, 1993, RUNAWAY CHEM REACTIO
[3]   PRACTICALLY ORIENTED REPRESENTATION OF THERMAL SAFETY LIMITS FOR AN INDIRECTLY COOLED SEMI-BATCH REACTOR [J].
HUGO, P ;
STEINBACH, J .
CHEMIE INGENIEUR TECHNIK, 1985, 57 (09) :780-782
[4]   A GENERALIZED CRITERION FOR PARAMETRIC SENSITIVITY - APPLICATION TO THERMAL-EXPLOSION THEORY [J].
MORBIDELLI, M ;
VARMA, A .
CHEMICAL ENGINEERING SCIENCE, 1988, 43 (01) :91-102
[5]   THERMALLY SAFE OPERATION OF A SEMIBATCH REACTOR FOR LIQUID LIQUID REACTIONS - SLOW REACTIONS [J].
STEENSMA, M ;
WESTERTERP, KR .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1990, 29 (07) :1259-1270
[6]  
Steensma M., 1991, CHEM ENG TECHNOL, V14, P367
[7]   A GENERAL-METHOD FOR ASSESSING THE THERMAL-STABILITY OF BATCH CHEMICAL REACTORS BY SENSITIVITY CALCULATION BASED ON LYAPUNOV EXPONENTS [J].
STROZZI, F ;
ZALDIVAR, JM .
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (16) :2681-2688
[8]   DETERMINING LYAPUNOV EXPONENTS FROM A TIME-SERIES [J].
WOLF, A ;
SWIFT, JB ;
SWINNEY, HL ;
VASTANO, JA .
PHYSICA D, 1985, 16 (03) :285-317