Aromatic and benzylic C-H bond activation in the system bis(dicarbonylrhodium(I))-porphyrinate - Hydrocarbon solvent

被引：22

作者：

Collman, JP ^{[1
]}

Boulatov, R ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 10期

关键词：

D O I：

10.1021/ic0011112

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metalation of C6H6 has been known for a long time as a side reaction occurring in refluxing benzene solutions of Rh-2(CO)(4)(TPP) (TTP = tetraphenylporphyrin). Rather than representing the intrinsic reactivity of this complex, such hydrocarbon activation proceeds via Rh-II(por) and Rh-III(por) derivatives resulting from oxidation of Rh-2(CO)(4)(TPP) with adventitious H2O and/or O-2. This reaction can be extended to other aromatic substrates and represents an efficient synthetic route to certain organometallic Rh-III(TPP) derivatives. [GRAPHICS]

引用

收藏

页码：2461 / +

页数：5

相关论文

共 36 条

[1] DICARBONYLRHODIUM(1) COMPLEXES OF POLYPYRROLE MACROCYCLES .1. PREPARATION AND OXIDATIVE ADDITION-REACTIONS WITH ALKYL-HALIDES AND CARBOXYLIC-ACID ANHYDRIDES [J].

ABEYSEKERA, AM ;

GRIGG, R ;

TROCHAGRIMSHAW, J ;

VISWANATHA, V .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (01) :36-44

[2] DICARBONYLRHODIUM(I) COMPLEXES OF POLYPYRROLE MACROCYCLES .2. OXIDATIVE ADDITION-REACTIONS WITH ALDEHYDES, FORMATES, BETA-OXO-ESTERS, METHYL KETONES, AND ARYL HALIDES [J].

ABEYSEKERA, AM ;

GRIGG, R ;

TROCHAGRIMSHAW, J ;

VISWANATHA, V .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (12) :1395-1403

[3]

[Anonymous], PORPHYRIN HDB

[4] ACTIVATION OF ARENE CARBON HYDROGEN-BONDS - HIGHLY REGIOSELECTIVE, ELECTROPHILIC AROMATIC METALATION WITH RHODIUM(III) PORPHYRIN AND SUBSEQUENT CLEAVAGE OF CARBON RHODIUM BOND [J].

AOYAMA, Y ;

YOSHIDA, T ;

SAKURAI, K ;

OGOSHI, H .

ORGANOMETALLICS, 1986, 5 (01) :168-173

[5] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION [J].

ARNDTSEN, BA ;

BERGMAN, RG ;

MOBLEY, TA ;

PETERSON, TH .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :154-162

[6]

Banerjee R, 1999, CHEM BIOCH B12

[7] A PHYSICAL ORGANIC ROAD TO ORGANOMETALLIC C-H OXIDATIVE ADDITION-REACTIONS [J].

BERGMAN, RG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 400 (1-2) :273-282

[8] The mechanism of a C-H bond activation reaction in room-temperature alkane solution [J].

Bromberg, SE ;

Yang, H ;

Asplund, MC ;

Lian, T ;

McNamara, BK ;

Kotz, KT ;

Yeston, JS ;

Wilkens, M ;

Frei, H ;

Bergman, RG ;

Harris, CB .

SCIENCE, 1997, 278 (5336) :260-263

[9] Thermal, catalytic, regiospecific functionalization of alkanes [J].

Chen, HY ;

Schlecht, S ;

Semple, TC ;

Hartwig, JF .

SCIENCE, 2000, 287 (5460) :1995-1997

[10] THERMODYNAMIC STUDIES OF COMPETITIVE ADDUCT FORMATION - SINGLE-INSERTION AND DOUBLE-INSERTION REACTIONS OF CARBON-MONOXIDE WITH RHODIUM OCTAETHYLPORPHYRIN DIMER [J].

COFFIN, VL ;

BRENNEN, W ;

WAYLAND, BB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) :6063-6069

← 1 2 3 4 →