Polymerization of methacrylates containing cationic cyclopentadienyliron moieties

被引：23

作者：

Abd-El-Aziz, AS ^{[1
]}

Todd, EK ^{[1
]}

Ma, GZ ^{[1
]}

DiMartino, J ^{[1
]}

机构：

[1] Univ Winnipeg, Dept Chem, Winnipeg, MB R3B 2E9, Canada

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS | 2000年 / 10卷 / 04期

关键词：

functionalized polymethacrylates; organoiron polymers; cationic cyclopentadienyliron complexes;

D O I：

10.1023/A:1016698924738

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel approach to the synthesis of polymethacrylates containing cationic cyclopentadienyliron moieties pendent to their side chains nas accomplished via the use of K-coordinated organoiron complexes. The complexed methacrylates were polymerized in the presence of AIBN to give soluble organoiron poly methacrylates (6a and 6b, 10. 14 and 14b) in 80 90% yields. Photolytic demetallation of the organoiron polymers allowed for the isolation of their organic analogues (7a and 7b, 11, 15a and 15b) whose weight average molecular weights ranged from 48.500 to 68,300.

引用

页码：265 / 272

页数：8

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