Novel elimination of hydroxylamine and formation of a nickel tetramer on reactions of glutarodihydroxamic acid with model dinickel hydrolases

被引：16

作者：

Brown, DA ^{[1
]}

Cuffe, LP

Deeg, O

Errington, W

Fitzpatrick, NJ

Glass, WK

Herlihy, K

Kemp, TJ

Nimir, H

机构：

[1] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Dublin 4, Ireland

[2] Univ Wurzburg, D-97070 Wurzburg, Germany

[3] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 22期

关键词：

D O I：

10.1039/a806911e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of glutarodihydroxamic acid with the hydrolase enzyme urease models, [N-2(mu-H2O)(OAc)(4)(tmen)(2)] and [Ni-2(OAc),(urea)(tmen)(2)][OTf], lead to novel hydroxylamine elimination and formation of [Ni-2(OAc)(2){mu-O(N)(OC)(2)(CH2)(3)} (tmen)(2)] [OTf] and the tetramer [Ni-4(OAc)(2)(gluA(2))(2)(tmen)(4)] [OTf](2), respectively, both of which are structurally characterised by X-ray crystallography.

引用

页码：2433 / 2434

页数：2

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