A third isolated oxidation state for the Mn12 family of single-molecule magnets

被引：99

作者：

Soler, M

Chandra, SK

Ruiz, D

Davidson, ER

Hendrickson, DN ^{[1
]}

Christou, G

机构：

[1] Univ Calif San Diego, Dept chem 0358, La Jolla, CA 92093 USA

[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 24期

关键词：

D O I：

10.1039/b006519f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dianionic members of the Mn-12 family of single-molecule magnets have been prepared by two-electron reduction of the neutral cluster; the [PPh4](2)[Mn12O12(O2CCHCl2)(16)- (H2O)(4)] representative has been shown to possess an S = 10 ground state and to exhibit out-of-phase ac susceptibility signals diagnostic of single-molecule magnetism behavior.

引用

收藏

页码：2417 / 2418

页数：2

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