A novel organic-inorganic hybrid material with fluorescent emission:: [Cd(PT)(H2O)]n (PT = phthalate)

被引：135

作者：

Wang, ST

Hou, Y

Wang, EB ^{[1
]}

Li, YG

Xu, L

Peng, J

Liu, SX

Hu, CW

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 07期

关键词：

D O I：

10.1039/b211358a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel organic-inorganic hybrid material [Cd(PT)(H2O)](n) (1; PT=phthalate) has been hydrothermally synthesized. The X-ray diffraction study reveals that 1 exhibits an interesting two-dimensional (2D) honeycomb framework constructed from [CdO7] single helical chains linked via oxygen atoms of the PT ligands, which adopt the mu(6)-bridging coordination mode. A study of the physical properties of 1 demonstrates that it exhibits a strong fluorescent emission in the solid state at room temperature.

引用

页码：1144 / 1147

页数：4

共 73 条

[1] Synthesis and X-ray diffraction study of Zn(II) complexes with o-phthalic acid and aromatic amines [J].