Nanorubbing of polythiophene surfaces

被引：50

作者：

Derue, G

Coppée, S

Gabriele, S

Surin, M

Geskin, V

Monteverde, F

Leclère, P

Lazzaroni, R

Damman, P

机构：

[1] Univ Mons, Serv Chim Mat Nouveaux, Lab Physicochim Polymeres, B-7000 Mons, Belgium

[2] Mat Nova, B-7000 Mons, Belgium

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 22期

关键词：

D O I：

10.1021/ja0505806

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work describes a new orientation method for semicrystalline poly(3-hexylthiophene) (P3HT) thin films, coupling nanorubbing and subsequent crystallization. Using the stylus of an atomic force microscope, we align the polymer chains on P3HT surfaces with a spatial and geometrical control of the oriented domains (nanorubbing). These chain-aligned structures can be made permanent thanks to the crystallization process, which propagates the orientation obtained at the surface to the bulk. Copyright © 2005 American Chemical Society.

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页码：8018 / 8019

页数：2

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