Trifluoromethylation and pentafluorophenylation of enamines

被引：11

作者：

Dilman, A. D. ^{[1
]}

Gorokhov, V. V. ^{[1
]}

Belyakov, P. A. ^{[1
]}

Struchkova, M. I. ^{[1
]}

Tartakovsky, V. A. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 08期

关键词：

silanes; iminium cations; pentacoordinate silicon; amines; enamines; organosilicon compounds; organofluorine compounds;

D O I：

10.1007/s11172-007-0235-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A reaction of enamines with Me3SiCF3 and Me3SiC6F5 in the presence of carboxylic acids leading to alpha-CF3- and alpha-C6F5-substituted amines has been studied. 3-Cyanobenzoic acid was found to be the optimal promoter of these reactions.

引用

页码：1522 / 1525

页数：4

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