Heating effect on manganese oxihydroxides used as black Palaeolithic pigment

被引：20

作者：

Chalmin, E. ^{[1
,2
]}

Vignaud, C. ^{[1
]}

Farges, F. ^{[3
,4
]}

Menu, M. ^{[1
]}

机构：

[1] CNRS, UMR 171, Ctr Rech & Restaurat Musees France, Paris, France

[2] European Synchrotron Radiat Facil, F-38043 Grenoble, France

[3] Stanford Univ, Dept Geog & Environm Sci, Stanford, CA 94305 USA

[4] CNRS, UMR 7160, USM 201 Mineral, Museum Natl Hist Nat, Paris, France

来源：

PHASE TRANSITIONS | 2008年 / 81卷 / 2-3期

关键词：

manganese oxi(hydroxi)des; heat treatment; Palaeolithic pigment; TEM; In situ TEM; XANES;

D O I：

10.1080/01411590701514359

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Manganese oxihydroxide behaviour has been studied under heat treatment to understand the transformation mechanisms and subsequently to gain insights into the preparation procedures of black painting materials during the Palaeolithic period. These manganese oxihydroxides have been studied as a function of heat treatment by TEM, XRD, DTA and FTIR and XANES (Mn K-edge) spectroscopies. These materials have been used as black pigments during the Palaeolithic period to realise rock art paintings such as in Lascaux (Dordogne, France) and Gargas (Midi-Pyrnes, France). Specific morphological, chemical and structural criteria were determined to distinguish between natural and heat-treated pigments.

引用

页码：179 / 203

页数：25

共 42 条

[1]

AUJOULAT N, 2002, ACT C 10 JOURN ET SF, V5, P5

[2] Thermal stability and structural transition of metastable Mn5O8:: in situ micro-Raman study [J].

Azzoni, CB ;

Mozzati, MC ;

Galinetto, P ;

Paleari, A ;

Massarotti, V ;

Capsoni, D ;

Bini, M .

SOLID STATE COMMUNICATIONS, 1999, 112 (07) :375-378

[3]

Baron V, 1998, AM MINERAL, V83, P786

[4]

Brugger J, 1999, EUR J MINERAL, V11, P879

[5]

Bums R.G., 1977, Marine Manganese Deposits, P185

[6] Minerals discovered in paleolithic black pigments by transmission electron microscopy and micro-X-ray absorption near-edge structure [J].

Chalmin, E ;

Vignaud, C ;

Salomon, H ;

Farges, F ;

Susini, J ;

Menu, M .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2006, 83 (02) :213-218

[7] The "blazons" of the Lascaux Cave [J].

Chalmin, E ;

Menu, M ;

Pomiès, MP ;

Vignaud, C ;

Aujoulat, N ;

Geneste, JM .

ANTHROPOLOGIE, 2004, 108 (05) :571-592

[8] Palaeolithic painting matter: natural or heat-treated pigment? [J].

Chalmin, E ;

Vignaud, C ;

Menu, M .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2004, 79 (02) :187-191

[9]

CHALMIN E, IN PRESS PHYS CHEM M

[10]

Chalmin E., 2002, MUNIBE, V54, P35

← 1 2 3 4 5 →