Octaalkylphthalocyaninato ruthenium(II) complexes with mixed axial ligands and supramolecular porphyrin:phthalocyanine structures derived from them

被引：47

作者：

Cammidge, AN ^{[1
]}

Berber, G ^{[1
]}

Chambrier, I ^{[1
]}

Hough, PW ^{[1
]}

Cook, MJ ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci & Pharm, Wolfson Mat & Catalysis Ctr, Norwich NR4 7TJ, Norfolk, England

来源：

TETRAHEDRON | 2005年 / 61卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

ruthenium; phthalocyanine; porphyrin; supramolecular arrays;

D O I：

10.1016/j.tet.2005.02.027

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Complementary syntheses of 1,4,8,11,15,18,22,25-octakis(alkyl) substituted ruthenium phthalocyanines, in which either one or two axial ligands can be added, are described. Their utility in the preparation of further (pyridyl) ligated derivatives has been shown to be straightforward. The chemistry is sufficiently robust and efficient to permit elaborate, supramolecular complexes to be prepared, as demonstrated by the synthesis of porphyrin-phthalocyanine multichromophore arrays. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：4067 / 4074

页数：8

共 25 条

[1] Effect of molecular packing on the solid state spectra of ruthenium phthalocyanine: anomalous behaviour of a monodimensional stacked assembly [J].