A three-coordinate copper(I)-phenoxide complex that models the reduced form of galactose oxidase

被引:29
作者
Jazdzewski, BA
Young, VG
Tolman, WB
机构
[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
[2] Univ Minnesota, Ctr Met Biocatalysis, Minneapolis, MN 55455 USA
关键词
D O I
10.1039/a806749j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel 3-coordinate Cu(I)-phenoxide complex with N-donor supporting ligation was structurally characterized and shown to be highly reactive towards dioxygen, similar to the reduced form of galactose oxidase.
引用
收藏
页码:2521 / 2522
页数:2
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