Rhodamine-hydroxamate-based fluorescent chemosensor for FeIII

被引:126
作者
Bae, Shinhyo
Tae, Jinsung [1 ]
机构
[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
[2] Yonsei Univ, CBMH, Seoul 120749, South Korea
关键词
D O I
10.1016/j.tetlet.2007.06.014
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A hydroxamate-based chemosensor, which responds fluorescently and colorimetrically to Fe-III in micromolar ranges, has been developed. The rhodamine hydroxamate probe is prepared in two steps from rhodamine B base. The biomimetic hydroxamate binding site is attached to the rhodamine fluorophore to recognize Fe-III selectively over other biologically important metal ions. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5389 / 5392
页数:4
相关论文
共 45 条
[1]   Iron metabolism [J].
Aisen, P ;
Wessling-Resnick, M ;
Leibold, EA .
CURRENT OPINION IN CHEMICAL BIOLOGY, 1999, 3 (02) :200-206
[2]   Calcein as a fluorescent iron chemosensor for the determination of low molecular weight iron in biological fluids [J].
Ali, A ;
Zhang, Q ;
Dai, JS ;
Huang, X .
BIOMETALS, 2003, 16 (02) :285-293
[3]   Measuring picomolar intracellular exchangeable zinc in PC-12 cells using a ratiometric fluorescence biosensor [J].
Bozym, Rebecca A. ;
Thompson, Richard B. ;
Stoddard, Andrea K. ;
Fierke, Carol A. .
ACS CHEMICAL BIOLOGY, 2006, 1 (02) :103-111
[4]   On the development of sensor molecules that display FeIII-amplified fluorescence [J].
Bricks, JL ;
Kovalchuk, A ;
Trieflinger, C ;
Nofz, M ;
Büschel, M ;
Tolmachev, AI ;
Daub, J ;
Rurack, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13522-13529
[5]   Luminescent sensors and switches in the early 21st century [J].
Callan, JF ;
de Silva, AP ;
Magri, DC .
TETRAHEDRON, 2005, 61 (36) :8551-8588
[6]  
Connors K. A., 1987, BINDING CONSTANTS ME
[7]   CHEMICAL COMMUNICATION IN WATER USING FLUORESCENT CHEMOSENSORS [J].
CZARNIK, AW .
ACCOUNTS OF CHEMICAL RESEARCH, 1994, 27 (10) :302-308
[8]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[9]   Complex ions. II. The stability and activity coefficients of the silver-ammonia ion [J].
Derr, PF ;
Stockdale, RM ;
Vosburgh, WC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 :2670-2674
[10]   A long-wavelength fluorescent chemodosimeter selective for Cu(II) ion in water [J].
Dujols, V ;
Ford, F ;
Czarnik, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (31) :7386-7387