The Cu(OTf)2- and Yb(OTf)3-catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers

被引：38

作者：

Hiersemann, M ^{[1
]}

Abraham, L ^{[1
]}

机构：

[1] Tech Univ Dresden, Inst Organ Chem, D-01062 Dresden, Germany

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 01期

关键词：

D O I：

10.1021/ol006760w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The Cu(OTf)(2)- and Yb(OTf)(3)-catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers has been developed. Reactivity and stereoselectivity strongly depend on the substrate structure.

引用

页码：49 / 52

页数：4

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