Substituent-dependent selective replacement of alkyne moieties of zirconacyclopentadienes via C-C bond cleavage reaction

被引:37
作者
Hara, R
Xi, ZF
Kotora, M
Xi, CJ
Takahashi, T
机构
[1] HOKKAIDO UNIV, CATALYSIS RES CTR, KITA KU, SAPPORO, HOKKAIDO 060, JAPAN
[2] HOKKAIDO UNIV, GRAD SCH PHARMACEUT SCI, KITA KU, SAPPORO, HOKKAIDO 060, JAPAN
关键词
D O I
10.1246/cl.1996.1003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Replacement of an alkyne moiety of zirconacyclopentadienes via beta,beta'-carbon-carbon bond cleavage was highly dependent on their substituents, Complete differentiation between diphenylacetylene and 4-octyne in the reaction with butyronitrile was demonstrated.
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页码:1003 / 1004
页数:2
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