A discussion on the apparently puzzling structural, electrical and magnetic properties of BaVS3

被引：11

作者：

Whangbo, MH ^{[1
]}

Koo, HJ

Dai, D

Villesuzanne, A

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

[2] CNRS, ICMCB, F-33608 Pessac, France

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2003年 / 175卷 / 02期

关键词：

D O I：

10.1016/S0022-4596(03)00346-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ternary vanadium sulfide BaVS3 consists of VS3 chains made up of face sharing VS6 octahedra, and exhibits a number of structural, electrical and magnetic properties that are not explained in terms of the normal metallic state. Our analysis indicates that the spin ordering of BaVS3 taking place below 30 K is most probably random along the chain direction. Thus the puzzling properties of BaVS3 are explained in terms of the broken-symmetry electronic state in which pairs of nonmagnetic V atoms alternate with those of magnetic V atoms in each VS3 chain. The origin of this broken-symmetry state was discussed on the basis of cooperative Jahn-Teller distortion and lattice strain. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：384 / 388

页数：5

共 19 条

[1]

Blaha P., 2001, WIEN2K AUGMENTED PLA, V60, P1

[2] One-dimensional instability in BaVS3 -: art. no. 196401 [J].

Fagot, S ;

Foury-Leylekian, P ;

Ravy, S ;

Pouget, JP ;

Berger, H .

PHYSICAL REVIEW LETTERS, 2003, 90 (19) :4

[3] PREPARATION PROPERTIES AND CRYSTAL STRUCTURE OF BARIUM VANADIUM SULFIDE BAVS3 [J].

GARDNER, RA ;

VLASSE, M ;

WOLD, A .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 :781-+

[4] POWDER NEUTRON-DIFFRACTION STUDIES OF THE LOW-TEMPERATURE PHASE-TRANSITIONS IN STOICHIOMETRIC BAVS3 [J].

GHEDIRA, M ;

ANNE, M ;

CHENAVAS, J ;

MAREZIO, M ;

SAYETAT, F .

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1986, 19 (33) :6489-6503

[5] SUPPRESSION OF THE METAL-TO-INSULATOR TRANSITION IN BAVS3 WITH PRESSURE [J].

GRAF, T ;

MANDRUS, D ;

LAWRENCE, JM ;

THOMPSON, JD ;

CANFIELD, PC ;

CHEONG, SW ;

RUPP, LW .

PHYSICAL REVIEW B, 1995, 51 (04) :2037-2044

[6] HYPERFINE INTERACTION AND MAGNETIC PHASE-TRANSITION OF BAVS3 OBSERVED BY INELASTIC SPIN-FLIP SCATTERING OF NEUTRONS [J].

HEIDEMANN, A ;

TAKANO, M .

PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1980, 100 (01) :343-346

[7] Symmetry breaking in the metal-insulator transition of BaVS3 -: art. no. 073108 [J].

Inami, T ;

Ohwada, K ;

Kimura, H ;

Watanabe, M ;

Noda, Y ;

Nakamura, H ;

Yamasaki, T ;

Shiga, M ;

Ikeda, N ;

Murakami, Y .

PHYSICAL REVIEW B, 2002, 66 (07) :731081-731084

[8] BAVS3, A QUASI ONE DIMENSIONAL FERROMAGNET OR ANTI-FERROMAGNET DEPENDING ON STOICHIOMETRY [J].

MASSENET, O ;

BUDER, R ;

SINCE, JJ ;

SCHLENKER, C ;

MERCIER, J ;

KELBER, J ;

STUCKY, DG .

MATERIALS RESEARCH BULLETIN, 1978, 13 (03) :187-195

[9] MAGNETIC AND TRANSPORT-PROPERTIES OF BAV1-XTIXS3 (0-LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-0.2) [J].

MATSUURA, K ;

WADA, T ;

NAKAMIZO, T ;

YAMAUCHI, H ;

TANAKA, S .

PHYSICAL REVIEW B, 1991, 43 (16) :13118-13123

[10] ELECTRONIC-STRUCTURE OF QUASI-ONE-DIMENSIONAL BAVS3 [J].

MATTHEISS, LF .

SOLID STATE COMMUNICATIONS, 1995, 93 (10) :791-795

← 1 2 →