Tuning the moisture stability of metal-organic frameworks by incorporating hydrophobic functional groups at different positions of ligands

被引：254

作者：

Ma, Deyun ^{[1
]}

Li, Yingwei ^{[1
]}

Li, Zhong ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 26期

关键词：

HYDROGEN STORAGE; SEPARATION; MOF-5; WATER; AIR;

D O I：

10.1039/c1cc11752a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The introduction of hydrophobic groups (e.g. methyl) at the most adjacent sites of each and every coordinating nitrogen atom of the bipyridine pillar linker in a carboxylate-based bridging MOF could shield the metal ions from attack by water molecules, and thus enhance the water resistance of the MOF structure significantly.

引用

页码：7377 / 7379

页数：3

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