A systematic shift in the electronic spectra of substituted benzene molecules trapped in helium nanodroplets

被引：14

作者：

Boatwright, A ^{[1
]}

Besley, NA ^{[1
]}

Curtis, S ^{[1
]}

Wright, RR ^{[1
]}

Stace, AJ ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Dept Phys Chem, Nottingham NG7 2RD, England

来源：

JOURNAL OF CHEMICAL PHYSICS | 2005年 / 123卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1063/1.1988309

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electronic spectra (S-1 <- S-0) have been recorded from five separate substituted benzene derivatives trapped in helium nanodroplets. Each member of the series is found to exhibit a blueshift with respect to the equivalent transition in the gas phase. Taken together with previous results for benzene, the observed shifts show a remarkably good correlation with changes in electron density that occur within each of the aromatic rings as a result of electronic excitation. (c) 2005 American Institute of Physics.

引用

页数：3

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