Chromoionophores based on crown ethers and related structures for alkali metal ion sensing in aqueous media

被引：20

作者：

Hayashita, T ^{[1
]}

Teramae, N

Kuboyama, T

Nakamura, S

Yamamoto, H

Nakamura, H

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 98077, Japan

[2] Kyushu Univ, Grad Sch Engn, Dept Chem Syst & Engn, Higashi Ku, Fukuoka 812, Japan

[3] Tokuyama Soda Co Ltd, Tsukuba, Ibaragi 30042, Japan

[4] Hokkaido Univ, Grad Sch Environm Earth Sci, Div Mat Sci, Sapporo, Hokkaido 060, Japan

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1998年 / 32卷 / 2-3期

关键词：

chromoionophore; spherand; hemispherand; cryptand; crown ether; calix; 4; crown; colorimetry; aqueous media;

D O I：

10.1023/A:1008019612324

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent progress in chromoionophores based on (1) spherand and hemispherand, (2) cryptand, and (3) dibenzo-16-crown-5 and calix[4]crown which selectively respond to alkali metal ions in aqueous media is reviewed in relation to their molecular structure and photometric function. The design concept of the chromoionophores for colorimetry in aqueous media is discussed in the light of their acid dissociation and metal complex formation equilibria.

引用

页码：251 / 265

页数：15

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