Photoluminescent europium-containing inner sphere conducting metallopolymer

被引：119

作者：

Chen, Xiao-Yan ^{[1
,2
]}

Yang, Xiaoping ^{[1
,2
]}

Holliday, Bradley J. ^{[1
,2
]}

机构：

[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Univ Texas Austin, Ctr Nano & Mol Sci & Technol, Austin, TX 78712 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 05期

关键词：

D O I：

10.1021/ja077626a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidative electrochemical polymerization of a new Eu(III) complex that contains 3,4-ethylenedioxythenyl (EDOT) groups has been carried out, resulting in the formation of an inner sphere conducting metalopolymer. Preliminary photophysical measurements reveal energy transfer to the europium center and the corresponding stimulated red emission. Importantly, the europium-containing conducting metallopolymer displays only a europium-based emission profile leading to excellent color purity in this material.

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页码：1546 / +

页数：3

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