An environment-friendly preparation of reduced graphene oxide nanosheets via amino acid

被引:300
作者
Chen, Dezhi [1 ,2 ]
Li, Lidong [1 ]
Guo, Lin [1 ]
机构
[1] Beijing Univ Aeronaut & Astronaut, Sch Chem & Environm, Beijing 100191, Peoples R China
[2] Nanchang Hangkong Univ, Sch Environm & Chem Engn, Nanchang 330063, Peoples R China
基金
中国国家自然科学基金;
关键词
EXFOLIATED GRAPHITE OXIDE; VITAMIN-C; REDUCTION; SHEETS; FILMS; DISPERSIONS; SUSPENSIONS; ELECTRODES; DISULFIDE; ROUTE;
D O I
10.1088/0957-4484/22/32/325601
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Chemically modified graphene has been studied in many applications due to its excellent electrical, mechanical, and thermal properties. Among the chemically modified graphenes, reduced graphene oxide is the most important for its structure and properties, which are similar to pristine graphene. Here, we introduce an environment-friendly approach for preparation of reduced graphene oxide nanosheets through the reduction of graphene oxide that employs L-cysteine as the reductant under mild reaction conditions. The conductivity of the reduced graphene oxide nanosheets produced in this way increases by about 10(6) times in comparison to that of graphene oxide. This is the first report about using amino acids as a reductant for the preparation of reduced graphene oxide nanosheets, and this procedure offers an alternative route to large-scale production of reduced graphene oxide nanosheets for applications that require such material.
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页数:7
相关论文
共 38 条
[2]   Preparation of graphene by the rapid and mild thermal reduction of graphene oxide induced by microwaves [J].
Chen, Wufeng ;
Yan, Lifeng ;
Bangal, Prakriti R. .
CARBON, 2010, 48 (04) :1146-1152
[3]   Noncovalent functionalization of graphene with end-functional polymers [J].
Choi, Eun-Young ;
Han, Tae Hee ;
Hong, Jihyun ;
Kim, Ji Eun ;
Lee, Sun Hwa ;
Kim, Hyun Wook ;
Kim, Sang Ouk .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (10) :1907-1912
[4]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[5]   Chemically Derived Graphene Oxide: Towards Large-Area Thin-Film Electronics and Optoelectronics [J].
Eda, Goki ;
Chhowalla, Manish .
ADVANCED MATERIALS, 2010, 22 (22) :2392-2415
[6]   Deoxygenation of Exfoliated Graphite Oxide under Alkaline Conditions: A Green Route to Graphene Preparation [J].
Fan, Xiaobin ;
Peng, Wenchao ;
Li, Yang ;
Li, Xianyu ;
Wang, Shulan ;
Zhang, Guoliang ;
Zhang, Fengbao .
ADVANCED MATERIALS, 2008, 20 (23) :4490-4493
[7]   An environmentally friendly and efficient route for the reduction of graphene oxide by aluminum powder [J].
Fan, Zhuangjun ;
Wang, Kai ;
Wei, Tong ;
Yan, Jun ;
Song, Liping ;
Shao, Bo .
CARBON, 2010, 48 (05) :1686-1689
[8]   Vitamin C Is an Ideal Substitute for Hydrazine in the Reduction of Graphene Oxide Suspensions [J].
Fernandez-Merino, M. J. ;
Guardia, L. ;
Paredes, J. I. ;
Villar-Rodil, S. ;
Solis-Fernandez, P. ;
Martinez-Alonso, A. ;
Tascon, J. M. D. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (14) :6426-6432
[9]   Environment-Friendly Method To Produce Graphene That Employs Vitamin C and Amino Acid [J].
Gao, Jian ;
Liu, Fang ;
Liu, Yiliu ;
Ma, Ning ;
Wang, Zhiqiang ;
Zhang, Xi .
CHEMISTRY OF MATERIALS, 2010, 22 (07) :2213-2218
[10]  
Gao W, 2009, NAT CHEM, V1, P403, DOI [10.1038/NCHEM.281, 10.1038/nchem.281]