Synthesis of a well-defined epoxy copolymer by atom transfer radical polymerization

被引:16
作者
Chen, ZM [1 ]
Bao, HL [1 ]
Liu, JZ [1 ]
机构
[1] Southeast Univ, Dept Chem & Chem Engn, Nanjing 210096, Peoples R China
关键词
ATRP; amphiphilic; epoxy copolymer;
D O I
10.1002/pola.1333
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A new series of diamines, 4-aryl-2,6 bis(4-amino phenyl)pyridine, bearing bulky aromatic-type pendant groups were prepared and reacted with three different dianhydrides. The best conditions of polymerization and imidization were obtained via a study of model compound. All polyimides showed excellent thermal stability, and those based on hexafluoroisopropylidene-2.2-bis(phthalic-dianhydride) had very good solubility in polar aprotic solvents.
引用
收藏
页码:3726 / +
页数:8
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