Selective detection of D-lactulose by a porphyrin-based diboronic acid

被引：25

作者：

Kijima, H ^{[1
]}

Takeuchi, M ^{[1
]}

Shinkai, S ^{[1
]}

机构：

[1] Kyushu Univ, Fac Engn, Dept Chem Sci & Technol, Fukuoka 812, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 08期

关键词：

D O I：

10.1246/cl.1998.781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cis-5,15-bis[2-(dihydroxyboronyl)phenyl]-10,20-diphenylporphine (cis-DBPP) bearing two boronic acid groups in a 9 Angstrom distance has been synthesized. The absorption, fluorescence, and CD spectral changes were induced only by D-lactulose among 10 disaccharides tested herein. One can readily sense D-lactulose by the spectroscopic methods.

引用

页码：781 / 782

页数：2

共 16 条

[1]

Ferrier RJ, 1978, ADV CARBOHYD CHEM BI, V35, P31

[2] ION-RESPONSIVE FLUORESCENT COMPOUNDS .1. EFFECT OF CATION BINDING ON PHOTOPHYSICAL PROPERTIES OF A BENZOXAZINONE DERIVATIVE LINKED TO MONOAZA-15-CROWN-5 [J].

FERYFORGUES, S ;

LEBRIS, MT ;

GUETTE, JP ;

VALEUR, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (22) :6233-6237

[3] Effect of lactulose on short-chain fatty acids and lactate production and on the growth of faecal flora, with special reference to Clostridium difficile [J].

Ito, Y ;

Moriwaki, H ;

Muto, Y ;

Kato, N ;

Watanabe, K ;

Ueno, K .

JOURNAL OF MEDICAL MICROBIOLOGY, 1997, 46 (01) :80-84

[4] Fluorescent saccharide receptors: A sweet solution to the design, assembly and evaluation of boronic acid derived PET sensors [J].

James, TD ;

Linnane, P ;

Shinkai, S .

CHEMICAL COMMUNICATIONS, 1996, (03) :281-288

[5] Saccharide sensing with molecular receptors based on boronic acid [J].

James, TD ;

Sandanayake, KRAS ;

Shinkai, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (17) :1910-1922

[6] STABILIZATION OF SUGAR-BORONIC ESTERS OF INDOLYLBORONIC ACID IN WATER VIA SUGAR INDOLE INTERACTION - A NOTABLE SELECTIVITY IN OLIGOSACCHARIDES [J].

NAGAI, Y ;

KOBAYASHI, K ;

TOI, H ;

AOYAMA, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (10) :2965-2971

[7] MOLECULAR COMPLEXES AND THEIR SPECTRA .8. THE MOLECULAR COMPLEX BETWEEN IODINE AND TRIETHYLAMINE [J].

NAGAKURA, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (03) :520-534

[8] Boronic acids as fructose sensors. Structure determination of the complexes involved using (1)J(CC) coupling constants [J].

Norrild, JC ;

Eggert, H .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (12) :2583-2588

[9]

OGOSHI H, 1994, YUKAGAKU, V43, P11

[10] SPECIFIC RECOGNITION OF DISACCHARIDES BY TRANS-3,3'-STILBENEDIBORONIC ACID - RIGIDIFICATION AND FLUORESCENCE ENHANCEMENT OF THE STILBENE SKELETON UPON FORMATION OF A SUGAR-STILBENE MACROCYCLE [J].

SANDANAYAKE, KRAS ;

NAKASHIMA, K ;

SHINKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (14) :1621-1622

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