Amino functionalized zeolitic tetrazolate framework (ZTF) with high capacity for storage of carbon dioxide

被引:255
作者
Panda, Tamas [1 ]
Pachfule, Pradip [1 ]
Chen, Yifei [2 ]
Jiang, Jianwen [2 ]
Banerjee, Rahul [1 ]
机构
[1] Natl Chem Lab, Phys Mat Chem Div, Pune 411008, Maharashtra, India
[2] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117576, Singapore
关键词
METAL-ORGANIC FRAMEWORKS; IMIDAZOLATE FRAMEWORKS; CO2; BINDING; SEPARATION; CAPTURE; DESIGN; POWER; MOFS;
D O I
10.1039/c0cc04169f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A three dimensional -NH2 functionalized Zeolitic Tetrazolate Framework (ZTF-1) has been reported. The framework adopts a dia topology (M-L-M angle is close to 156 degrees). ZTF-1 shows high CO2 (273 K) and H-2 (77 K) uptake due to the presence of the free -NH2 group and uncoordinated tetrazolate nitrogen.
引用
收藏
页码:2011 / 2013
页数:3
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