A convenient one-pot synthesis of stannylsilanes

被引：9

作者：

Hummeltenberg, R ^{[1
]}

Jurkschat, K ^{[1
]}

Uhlig, F ^{[1
]}

机构：

[1] Univ Dortmund, Fachbereich Chem, Lehrstuhl Anorgan Chem 2, D-44221 Dortmund, Germany

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 123卷

关键词：

fluorosilanes; stannylsilanes; alpha; omega-; distannyloligosilanes; Si-29; Sn-119 NMR spectroscopy; FLUOROSILANES; HYDROSILANES; REAGENT;

D O I：

10.1080/10426509708044214

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stannylsilanes were synthesized in high yields by reaction of organotinchlorides with organofluorosilanes and magnesium. The fluorosilanes were prepared in good yields and under mild conditions by reaction of the corresponding chlorosilanes with [n-Bu4N][Ph3SnF2]. All products were characterized by Si-29, Sn-119 NMR spectroscopy and elemental analysis.

引用

页码：255 / 261

页数：7

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