Measurements of coexistence curves and turbidity for {xC6H5NO2+(1-x)CH3(CH2)6CH3} in the critical region

被引：18

作者：

An, XQ ^{[1
]}

Jiang, FG ^{[1
]}

Zhao, HH ^{[1
]}

Chen, CY ^{[1
]}

Shen, WG ^{[1
]}

机构：

[1] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1998年 / 30卷 / 06期

关键词：

critical phenomena; coexistence curve; turbidity; nitrobenzene; octane;

D O I：

10.1006/jcht.1997.0341

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The coexistence curves and the turbidity of (nitrobenzene + octane) have been measured and the critical amplitudes and exponents have been deduced. The values of exponents are consistent with theoretical predictions. The experimental results of coexistence curves have also been analysed to examine Wegner correction terms and the behaviour of the diameter of the coexistence curves in various units. A combination of the Wegner equation and the expression for the diameter has been used to describe successfully the coexistence curves. (C) 1998 Academic Press.

引用

页码：751 / 760

页数：10

共 22 条

[1]

ALPERT D, 1982, Z PHYS REV B, V25, P4810

[2]

AN X, IN PRESS ACTA CHIMIC

[3]

AN X, IN PRESS J CHEM THER

[4] Turbidity of critical solutions of polymethylmethacrylate in 3-octanone [J].

An, XQ ;

Shen, WG ;

Xia, KQ .

JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (06) :2060-2065

[5] The (liquid plus liquid) critical phenomena of (a polar liquid plus an n-alkane) .5. Coexistence curves of (N,N-dimethylacetamide plus heptane) [J].

An, XQ ;

Zhao, HH ;

Jiang, FG ;

Shen, WG .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1996, 28 (11) :1221-1232

[6] The coexistence curves of {x(CHCOOC2H5)(2)+(1-x)CH3(CH2)(6)CH3} in the critical region [J].

An, XQ ;

Liu, XH ;

Shen, WG .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1997, 29 (06) :669-675

[7]

AN XQ, 1993, J CHEM THERMODYN, V25, P1373

[8] The coexistence curves of {xC(6)H(5)NO(2)+(1-x)CH3(CH2)(12)CH3} in the critical region [J].

An, XQ ;

Zhao, HH ;

Jiang, FG ;

Mao, CF ;

Shen, WG .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1997, 29 (09) :1047-1054

[9]

An XQ, 1996, J CHEM THERMODYN, V28, P1165

[10]

BOTTCHER CJF, 1974, THEORY ELECT POLARIZ, V2, P288

← 1 2 3 →