Reactions of iridium and ruthenium arenethiolato complexes with propylene sulfide.: X-ray structures of 1-arylthio-2-propanethiolato-S,S′ iridium and ruthenium complexes

被引：10

作者：

Matsukawa, S ^{[1
]}

Kuwata, S ^{[1
]}

Hidai, M ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 10期

关键词：

crystal structures; iridium complexes; ruthenium complexes; thiolato complexes; thiiranes; thioether complexes;

D O I：

10.1016/S1387-7003(98)00094-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The square-planar iridium(I) thiolato complex [Ir(NO) (SMes)(2)(PPh3)] (1; Mes = Cd6H2Me3-2,4,6), which has been prepared by the reaction of [Ir(NO)Cl-2(PPh3)(2)] with NaSMes, reacted propylene with sulfide to afford the square-pyramidal 1-arylthio-2-propanethiolato iridium(III) complex [Ir(NO)(SMes)(SCHMeCH(2)SMes) (PPh3)] (2). Similar treatment of the ruthenium(IV) [Ru(NCMe)(SDur)(4)] (3; Dur=C6HMe4-2,3,5,6) resulted in the formation of the 1-aryltbio-3-propanethiolato complex [Ru(SDur)(3)(SCHMeCH(2)SDur)] ( 4) containing a trigonal-bipyramidal ruthenium(IV) center. The detailed structures of 2 and 4 have been determined by X-ray crystallography. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：368 / 371

页数：4

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