Highly selective synthesis of cataytically active monodisperse rhodium nanocubes

被引：218

作者：

Zhang, Yawen

Grass, Michael E.

Kuhn, John N.

Tao, Feng

Habas, Susan E.

Huang, Wenyu

Yang, Peidong

Somorjai, Gabor A. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem & Mat Sci, Berkeley, CA 94720 USA

[3] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 18期

关键词：

D O I：

10.1021/ja801210s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monodisperse sub-10 nm Rh nanocubes were synthesized with high selectivity (>85%) by a seedless polyol method. The (100) faces of the Rh NCs were effectively stabilized by chemically adsorbed Br ions from trimethyl(tetradecyl)ammonium bromide (TTAB). This simple one-step polyol route can be readily applied to the preparation of Pt and Pd nanocubes. Moreover, the organic molecules of PVP and TTAB that encapsulated the Rh nanocubes did not prevent catalytic activity for pyrrole hydrogenation and CO oxidation.

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页码：5868 / +

页数：3

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