Theory of copolymer micellization

被引：30

作者：

Duque, D ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Phys, Burnaby, BC V5A 1S6, Canada

来源：

JOURNAL OF CHEMICAL PHYSICS | 2003年 / 119卷 / 11期

关键词：

D O I：

10.1063/1.1599279

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We consider the micellization of block copolymers in solution, employing self-consistent field theory with an additional constraint that permits the examination of intermediate structures. From the information for an isolated micelle (structure, binding energy, free energy) we describe how the global thermodynamics of these systems can be obtained, which can be used to build a realistic phase diagram; the role of translational entropy must be addressed in this regard. (C) 2003 American Institute of Physics.

引用

页码：5701 / 5704

页数：4

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