An elimination reaction of N-carbomethoxy-N,N-dimethylhydrazonium salts to alkyl nitriles

被引：8

作者：

Xiao, ZJ ^{[1
]}

Timberlake, JW ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 42期

关键词：

D O I：

10.1016/S0040-4020(98)00787-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new kind of elimination of hydrazonium salts to alkyl nitriles has been developed. The reaction of hydrazones and chloroformates results in the formation of hydrazonium salts, which react in situ with water to afford alkyl nitriles. The elimination is adapted to a range of solvents and gives good yields of a-secondary and tertiary alkyl-substituted nitriles. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：12715 / 12720

页数：6

共 7 条

[1] THE CHEMISTRY OF ALIPHATIC AND ALICYCLIC NITRO COMPOUNDS .9. THE MECHANISM OF THE REACTION OF SILVER NITRITE WITH ALKYL HALIDES - THE CONTRASTING REACTIONS OF SILVER AND ALKALI METAL SALTS WITH ALKYL HALIDES - THE ALKYLATION OF AMBIDENT ANIONS [J].