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A commercially available perfectly hydrophobic material (θA/θR=180°/180°)
被引:72
作者:
Gao, Lichao
[1
]
McCarthy, Thomas J.
[1
]
机构:
[1] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
来源:
关键词:
SURFACES;
D O I:
10.1021/la701097k
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
We report contact angle studies of compressed samples of a commercially available lubricant (variable diameter submicrometer particles of tetrafluoroethylene oligomers) that indicate that this surface is perfectly hydrophobic (theta(A)/theta(R) = 180 degrees/180 degrees). We also report X-ray photoelectron spectroscopy (XPS) spectra, a scanning electron microscopy (SEM) micrograph, and F-19 NMR characterization data, as it is a material for which no characterization data are available. These samples exhibit the most general lyophobicity of any material reported, showing nearly 180 degrees contact angles with other liquids. That this material is commercially available (in kilogram quantities) will allow other groups, particularly nonsynthetic ones, to prepare and study perfectly hydrophobic surfaces. It should also have an impact on education: demonstration of superhydrophobicity in classrooms is trivial to do with this material.
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页码:9125 / 9127
页数:3
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