Chromophores in nanochannels for energy transfer and conversion

被引:12
作者
Botta, C
Destri, S
Pasini, M
Picouet, P
Bongiovanni, G
Mura, A
Uslenghi, M
Di Silvestro, G
Tubino, R
机构
[1] CNR, Ist Studio Macromol, I-20133 Milan, Italy
[2] Univ Cagliari, INFM, I-09042 Monserrato, Ca, Italy
[3] Univ Cagliari, Dipartimento Fis, I-09042 Monserrato, Ca, Italy
[4] CNR, Ist Astrofis Spaziale & Fis Cosmica, I-20133 Milan, Italy
[5] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy
[6] Univ Milan, INFM, I-20126 Milan, Italy
[7] Univ Milan, Dipartimento Sci Mat, I-20126 Milan, Italy
关键词
host-guest systems; energy transfer; photoluminescence;
D O I
10.1016/S0379-6779(03)00268-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Host-guest organic systems obtained by the inclusion of thiophene and phenylene based molecules in perhydrotriphenylene (PHTP) display efficient resonant energy transfers (RET) from short wavelength to longer wavelength emitters. The quantum efficiency of the longer wavelength emitter is lowered of about 20% when donor-acceptor transfer steps are required. A co-inclusion compound (IC) obtained with three molecules shows an efficient conversion of the near ultra violet (250-400 nm) energy into visible (400-600 nm) light with a high photoluminescence (PL) quantum yield (QY) of 45-60%. A proper design of host-guest materials exploiting energy transfer processes can provide interesting artificial nanostructures for optoelectronic applications. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:791 / 794
页数:4
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