Influence of crystallite size on the properties of zirconia

被引：124

作者：

Stichert, W ^{[1
]}

Schuth, F ^{[1
]}

机构：

[1] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 07期

关键词：

D O I：

10.1021/cm980705o

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Systematic studies on the properties of zirconia for catalytic applications revealed that the concentration of the stock solution, from which precipitation is carried out, strongly influence the crystallite size of the resulting zirconia. The crystallite size influences the BET surface area, the crystallization temperature, and the phase transition temperature. The findings of this study clarify the parameters governing the formation of specific phase with desired surface areas.

引用

页码：2020 / 2026

页数：7

共 45 条

[1] THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].

BARRETT, EP ;

JOYNER, LG ;

HALENDA, PP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380

[2] Adsorption of gases in multimolecular layers [J].

Brunauer, S ;

Emmett, PH ;

Teller, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319

[3] PREPARATION OF STABLE, HIGH-SURFACE-AREA ZIRCONIA [J].

CHAN, KS ;

CHUAH, GK ;

JAENICKE, S .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1994, 13 (21) :1579-1581

[4] STATISTICS OF MARTENSITIC NUCLEATION [J].

CHEN, IW ;

CHIAO, YH ;

TSUZAKI, K .

ACTA METALLURGICA, 1985, 33 (10) :1847-1859

[5] THEORY AND EXPERIMENT OF MARTENSITIC NUCLEATION IN ZRO2 CONTAINING CERAMICS AND FERROUS-ALLOYS [J].

CHEN, IW ;

CHIAO, YH .

ACTA METALLURGICA, 1985, 33 (10) :1827-1845

[6] CRYSTALLINE HYDROUS ZIRCONIA [J].

CLEARFIELD, A .

INORGANIC CHEMISTRY, 1964, 3 (01) :146-&

[7] THE MECHANISM OF HYDROLYTIC POLYMERIZATION OF ZIRCONYL SOLUTIONS [J].

CLEARFIELD, A .

JOURNAL OF MATERIALS RESEARCH, 1990, 5 (01) :161-162

[8] NATURE OF HYDROUS ZIRCONIA AND SULFATED HYDROUS ZIRCONIA [J].

CLEARFIELD, A ;

SERRETTE, GPD ;

KHAZISYED, AH .

CATALYSIS TODAY, 1994, 20 (02) :295-312

[9]

DAVIS BH, 1984, J AM CERAM SOC, V67, P168

[10] STABILIZATION OF TETRAGONAL STRUCTURE IN ZIRCONIA MICROCRYSTALS [J].

GARVIE, RC .

JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (02) :218-224

← 1 2 3 4 5 →