Chiral ferrocenyl diphosphines for asymmetric transfer hydrogenation of acetophenone

被引：17

作者：

Cabou, J ^{[1
]}

Brocard, J ^{[1
]}

Pélinski, L ^{[1
]}

机构：

[1] ENSCL, CNRS, UMR 8010, Lab Catalyse Lille, F-59652 Villeneuve Dascq, France

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 07期

关键词：

diphosphines; ferrocene; transfer hydrogenation;

D O I：

10.1016/j.tetlet.2004.12.059

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of new optically pure ferrocenyl diphosphines have been realized from (R)-(+)-N,N-dimethylaminoethyl-ferrocene. Particularly, dissymmetric ferrocenyl diphosphines have been synthesized. The diphosphines have been used as ligands in asymmetric transfer hydrogenation of acetophenone in the presence of Ru catalysts. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：1185 / 1188

页数：4

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