ortho-Metalation of Iron(0) Tribenzylphosphine Complexes: Homogeneous Catalysts for the Generation of Hydrogen from Formic Acid

被引：102

作者：

Boddien, Albert ^{[2
]}

Gaertner, Felix ^{[2
]}

Jackstell, Ralf ^{[2
]}

Junge, Henrik ^{[2
]}

Spannenberg, Anke ^{[2
]}

Baumann, Wolfgang ^{[2
]}

Ludwig, Ralf ^{[1
]}

Beller, Matthias ^{[2
]}

机构：

[1] Univ Rostock, Inst Chem, Phys Chem Abt, D-18059 Rostock, Germany

[2] Univ Rostock, Leibniz Inst Katalyse EV, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 47期

关键词：

formic acid; homogeneous catalysis; hydrogen storage; iron; ortho-metalation; STORAGE MATERIAL; DECOMPOSITION; FUEL; ADDUCTS;

D O I：

10.1002/anie.201004621

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Without noble metals: A new catalyst derived from a non-noble metal has been developed for the selective generation of hydrogen from formic acid. DFT calculations and NMR spectroscopy support the formation of active ortho-metalated iron species as key intermediates during catalysis. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8993 / 8996

页数：4

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