Mechanism of superprotonic conductivity in CsHSO4

被引：17

作者：

Belushkin, AV ^{[1
]}

McGreevy, RL

Zetterstrom, P

Shuvalov, LA

机构：

[1] Joint Inst Nucl Res, Frank Lab Neutron Phys, Dubna 141980, Moscow Region, Russia

[2] Uppsala Univ, NFL Studsvik, S-61182 Nykoping, Sweden

[3] Russian Acad Sci, Inst Cristallog, Moscow 117333, Russia

来源：

PHYSICA B | 1997年 / 241卷

关键词：

superprotonic conductor; proton diffusion; reverse Monte Carlo modelling;

D O I：

10.1016/S0921-4526(97)00574-7

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Cesium hydrogen sulphate is one of the most extensively studied superprotonic conductors with hydrogen bonds. The first-order phase transition, from the low-conductivity to high conductivity phase takes place at 414 K. The crystallographic structure of both phases has been established using high-resolution powder diffraction. Quasi-elastic neutron scattering gave information about the spatial and temporal characteristics of proton transport. The present paper reports the results of reverse Monte Carlo modelling of diffraction data which makes it possible to obtain the diffusion pathways for protons. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：323 / 325

页数：3

共 4 条

[1]

BARANOV AI, 1982, JETP LETT+, V36, P459

[2] HIGH-RESOLUTION NEUTRON POWDER DIFFRACTION STUDIES OF THE STRUCTURE OF CSDSO4 [J].

BELUSHKIN, AV ;

DAVID, WIF ;

IBBERSON, RM ;

SHUVALOV, LA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :161-166

[3] THE DIFFUSION OF PROTONS IN THE SUPERIONIC CONDUCTOR CSHSO4 BY QUASI-ELASTIC NEUTRON-SCATTERING [J].

BELUSHKIN, AV ;

CARLILE, CJ ;

SHUVALOV, LA .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1992, 4 (02) :389-398

[4] RMC - PROGRESS, PROBLEMS AND PROSPECTS [J].

MCGREEVY, RL .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1995, 354 (01) :1-16

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