Optical properties and characteristics of ZnS nanoparticles with homogeneous Mn distribution

被引：158

作者：

Yu, I

Isobe, T

Senna, M

机构：

[1] Keio University, Department of Applied Chemistry, Faculty of Science and Technology, Yokohama, 223, 3-14-1 Hiyoshi, Kohoku-ku

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1996年 / 57卷 / 04期

关键词：

D O I：

10.1016/0022-3697(95)00285-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unique properties of nano-particles of Mn-doped ZnS prepared by a new chemical process are studied. Homogeneously Mn-doped ZnS nano-particles, as demonstrated from electron spin resonance (ESR), were accomplished by precipitation in a methanolic media with the aid of methacrylic acid at room temperature. Photoluminescence (PL) intensity of ZnS nano-particles increased with decreasing particle size. Quantum size effects were confirmed from the blue shift in the optical band gap of ZnS nano-particles. The enhanced PL intensity was also explained by the nanosize effect.

引用

页码：373 / 379

页数：7

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