Reactions of acyl nitroso compounds with amines: Production of nitroxyl (HNO) with the preparation of amides

被引：38

作者：

Atkinson, RN ^{[1
]}

Storey, BM ^{[1
]}

King, SB ^{[1
]}

机构：

[1] WAKE FOREST UNIV,DEPT CHEM,WINSTON SALEM,NC 27109

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(97)82943-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of hydroxamic acids in the presence of amines generates nitrous oxide (N2O) and the corresponding amide. The identification of N2O suggests the intermediacy of nitroxyl (HNO). Reto-Diels Alder dissociation of cyclopentadiene-acyl nitroso compound cycloadducts releases N2O with amide formation. Copyright (C) 1996 Elsevier Science Ltd

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页码：9287 / 9290

页数：4

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