Environment-friendly soy flour-based resins without formaldehyde

被引:126
作者
Amaral-Labat, G. A. [1 ,2 ]
Pizzi, A. [1 ]
Goncalves, A. R. [2 ,3 ]
Celzard, A. [1 ,3 ]
Rigolet, S. [4 ]
Rocha, G. J. M. [2 ]
机构
[1] Univ Nancy 1, ENSTIB, F-54013 Epinal, France
[2] Univ Sao Paulo, Escuela Engn Lorena, Lorena, Brazil
[3] Univ Nancy 1, LCSM, Nancy, France
[4] Univ Haute Alsace, ENSCMu, Mulhouse, France
关键词
adhesives; soy; tannins; lignin; resins; wood; glyoxal; formaldehyde emission;
D O I
10.1002/app.27692
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Glyoxalated soy flour adhesives for wood particleboard added with a much smaller proportion of glyoxalated lignin or tannin and without any addition of either formaldehyde or formaldehyde-based resin are shown to yield results satisfying the relevant standard specifications for interior wood boards. Adhesive resin formulations in which the total content of natural material is either 70 or 80% of the total resin solids content gave good results. The resins comprising 70% by weight of natural material can be used in a much lower proportion on wood chips and can afford pressing times fast enough to be significant under industrial panel pressing conditions. The best formulation of all the ones tried was the one based on glyoxalated precooked soy flour (SG), to which a condensed tannin was added in water solution and a polymeric isocyanate (pMDI), where the proportions of the components SG/T/pMDI was 54/16/30 by weight. (C) 2008 Wiley Periodicals, Inc.
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页码:624 / 632
页数:9
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