Dioxygen activation by a neutral β-diketiminato copper(I) ethylene complex

被引：128

作者：

Dai, XL ^{[1
]}

Warren, TH ^{[1
]}

机构：

[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 19期

关键词：

D O I：

10.1039/b105244f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and structure of two thermally stable neutral beta -diketiminato copper(I) olefin complexes are presented along with the structure of a Cu(II)2(mu -OH)(2) dimer that results from the reaction of the Cu(I) ethylene complex with O-2 via the proposed intermediacy of a Cu(III)(2)(mu -O)(2) species.

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页码：1998 / 1999

页数：2

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