Watching GaN nanowires grow

被引:166
作者
Stach, EA [1 ]
Pauzauskie, PJ
Kuykendall, T
Goldberger, J
He, RR
Yang, PD
机构
[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Natl Ctr Electron Microscopy, Div Sci Mat, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
D O I
10.1021/nl034222h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report real-time high temperature transmission electron microscopy observations of the growth of GaN nanowires via a self-catalytic vapor-liquid-solid (VLS) mechanism. High temperature thermal decomposition of GaN in a vacuum yields nanoscale Ga liquid droplets and gallium/nitrogen vapor species for the subsequent GaN nanowire nucleation and growth. This is the first direct observation of self-catalytic growth of nanowires; via the VLS mechanism and suggests new strategies for synthesizing electronically pure single-crystalline semiconductor nanowires.
引用
收藏
页码:867 / 869
页数:3
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