Direct C-H carboxylation with complexes of the coinage metals

被引:133
作者
Boogaerts, Ine I. F. [1 ]
Nolan, Steven P. [1 ]
机构
[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland
基金
英国工程与自然科学研究理事会;
关键词
N-HETEROCYCLIC CARBENES; CATALYZED DIRECT CARBOXYLATION; CARBON-DIOXIDE; HOMOGENEOUS CATALYSIS; ACTIVATION; CO2; COPPER; PALLADIUM; ESTERS; BONDS;
D O I
10.1039/c0cc03890c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Advances into the functionalisation of C-H bonds by coinage metal complexes that make use of carbon dioxide are described. © 2011 Royal Society of Chemistry.
引用
收藏
页码:3021 / 3024
页数:4
相关论文
共 87 条
[1]   Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons [J].
Aoki, M ;
Kaneko, M ;
Izumi, S ;
Ukai, K ;
Iwasawa, N .
CHEMICAL COMMUNICATIONS, 2004, (22) :2568-2569
[2]   Catalysis research of relevance to carbon management: Progress, challenges, and opportunities [J].
Arakawa, H ;
Aresta, M ;
Armor, JN ;
Barteau, MA ;
Beckman, EJ ;
Bell, AT ;
Bercaw, JE ;
Creutz, C ;
Dinjus, E ;
Dixon, DA ;
Domen, K ;
DuBois, DL ;
Eckert, J ;
Fujita, E ;
Gibson, DH ;
Goddard, WA ;
Goodman, DW ;
Keller, J ;
Kubas, GJ ;
Kung, HH ;
Lyons, JE ;
Manzer, LE ;
Marks, TJ ;
Morokuma, K ;
Nicholas, KM ;
Periana, R ;
Que, L ;
Rostrup-Nielson, J ;
Sachtler, WMH ;
Schmidt, LD ;
Sen, A ;
Somorjai, GA ;
Stair, PC ;
Stults, BR ;
Tumas, W .
CHEMICAL REVIEWS, 2001, 101 (04) :953-996
[3]   Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].
Aresta, Michele ;
Dibenedetto, Angela .
DALTON TRANSACTIONS, 2007, (28) :2975-2992
[4]  
AVE H, 1994, CHEM COMMUN, P1197
[5]   Straightforward synthesis of donor-stabilised phosphenium adducts from imidazolium-2-carboxylate and their electronic properties [J].
Azouri, Michele ;
Andrieu, Jacques ;
Picquet, Michel ;
Richard, Philippe ;
Hanquet, Bernard ;
Tkatchenko, Igor .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 31 (31) :4877-4883
[6]   CARBON-DIOXIDE AS AN ALTERNATIVE C1 SYNTHETIC UNIT - ACTIVATION BY TRANSITION-METAL COMPLEXES [J].
BEHR, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (05) :661-678
[7]  
Benitez D, 2009, NAT CHEM, V1, P482, DOI [10.1038/NCHEM.331, 10.1038/nchem.331]
[8]   C-H Bond Activation by [{(Diimine)Pd(μ-OH)}2]2+ Dimers: Mechanism-Guided Catalytic Improvement [J].
Bercaw, John E. ;
Hazari, Nilay ;
Labinger, Jay A. ;
Oblad, Paul F. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (51) :9941-9943
[9]   Carboxylation of N-H/C-H Bonds Using N-Heterocyclic Carbene Copper(I) Complexes [J].
Boogaerts, Ine I. F. ;
Fortman, George C. ;
Furst, Marc R. L. ;
Cazin, Catherine S. J. ;
Nolan, Steven P. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (46) :8674-8677
[10]   Carboxylation of C-H Bonds Using N-Heterocyclic Carbene Gold(I) Complexes [J].
Boogaerts, Ine I. F. ;
Nolan, Steven P. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8858-+