High-performance carbon counter electrode for dye-sensitized solar cells

被引：656

作者：

Imoto, K

Takahashi, K ^{[1
]}

Yamaguchi, T

Komura, T

Nakamura, J

Murata, K

机构：

[1] Kanazawa Univ, Fac Engn, Dept Chem & Chem Engn, Kanazawa, Ishikawa 9208667, Japan

[2] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Innovat Technol & Sci, Kanazawa, Ishikawa 9208667, Japan

[3] Nippon Shokubai Co Ltd, Performance Chem & Mat Res Ctr, Suita, Osaka 5648512, Japan

[4] Nippon Shokubai Co Ltd, New Business Planning, Osaka 5640041, Japan

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2003年 / 79卷 / 04期

关键词：

dye-sensitized solar cell; activated carbon electrode; titanium dioxide;

D O I：

10.1016/S0927-0248(03)00021-7

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Here, we reported that a new carbon electrode prepared with an activated carbon was superior to a Pt sputtered electrode as the counter electrode of dye-sensitized solar cells. The photovoltaic performance was largely influenced by the roughness factor of carbon electrode. The open-circuit voltage increased by about 60 mV using the carbon counter electrode compared to the Pt counter electrode because of positive shift of the formal potential for I-3(-)/I- couple. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：459 / 469

页数：11

相关论文

共 15 条

[1] CHEMICAL MODIFICATION OF A TITANIUM(IV) OXIDE ELECTRODE TO GIVE STABLE DYE SENSITIZATION WITHOUT A SUPERSENSITIZER [J].

ANDERSON, S ;

CONSTABLE, EC ;

DAREEDWARDS, MP ;

GOODENOUGH, JB ;

HAMNETT, A ;

SEDDON, KR ;

WRIGHT, RD .

NATURE, 1979, 280 (5723) :571-573

[2] HIGHLY EFFICIENT SENSITIZATION OF TITANIUM-DIOXIDE [J].

DESILVESTRO, J ;

GRATZEL, M ;

KAVAN, L ;

MOSER, J ;

AUGUSTYNSKI, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (10) :2988-2990

[3]

Fujishima A., 1971, SEISAN KENKYU, V23, P363

[4] SENSITIZATION OF CHARGE INJECTION INTO SEMICONDUCTORS WITH LARGE BAND GAP [J].

GERISCHE.H ;

MICHELBE.ME ;

REBENTRO.F ;

TRIBUTSC.H .

ELECTROCHIMICA ACTA, 1968, 13 (06) :1509-&

[5] NEW EXPERIMENTS ON SENSITIZATION OF ZINC OXIDE BY MEANS OF ELECTROCHEMICAL CELL TECHNIQUE [J].

HAUFFE, K ;

DANZMANN, HJ ;

PUSCH, H ;

RANGE, J ;

VOLZ, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1970, 117 (08) :993-&

[6] Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder [J].

Kay, A ;

Gratzel, M .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1996, 44 (01) :99-117

[7] ELECTROCHEMICAL INVESTIGATIONS ON SPECTRAL SENSITIZATION OF GALLIUM PHOSPHIDE ELECTRODES [J].

MEMMING, R ;

TRIBUTSC.H .

JOURNAL OF PHYSICAL CHEMISTRY, 1971, 75 (04) :562-&

[8] CONVERSION OF LIGHT TO ELECTRICITY BY CIS-X2BIS(2,2'-BIPYRIDYL-4,4'-DICARBOXYLATE)RUTHENIUM(II) CHARGE-TRANSFER SENSITIZERS (X = CL-, BR-, I-, CN-, AND SCN-) ON NANOCRYSTALLINE TIO2 ELECTRODES [J].

NAZEERUDDIN, MK ;

KAY, A ;

RODICIO, I ;

HUMPHRYBAKER, R ;

MULLER, E ;

LISKA, P ;

VLACHOPOULOS, N ;

GRATZEL, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6382-6390

[9] A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS [J].

OREGAN, B ;

GRATZEL, M .

NATURE, 1991, 353 (6346) :737-740

[10] An iodine/triiodide reduction electrocatalyst for aqueous and organic media [J].

Papageorgiou, N ;

Maier, WF ;

Gratzel, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (03) :876-884