Surface and bulk stillwellite textures in glasses of the La2O3-B2O3-GeO2 system

被引:19
作者
Sigaev, VN
Sarkisov, PD
Pernice, P
Aronne, A
Datsenko, AM
Stefanovich, SY
Fertikov, VI
Pozhogin, OA
Zakharkin, DA
机构
[1] Univ Naples Federico II, Dept Mat & Prod Engn, I-80125 Naples, Italy
[2] Mendeleev Univ Chem Technol Russia, Moscow 125190, Russia
[3] LY Karpov Phys Chem Res Inst, Moscow 103064, Russia
基金
俄罗斯基础研究基金会;
关键词
pyroelectricity; stillewellite; texture;
D O I
10.1016/S0955-2219(03)00424-2
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Both surface and bulk textures penetrating the whole volume of the glass may be formed in glasses of the La2O3-B2O3-GeO2 system near the stoichiometry of LaBGeO5 stillwellite. These textures cause non-linear optic, ferroelectric and pyroelectric properties of crystallized glasses. The present work represents SEM study of surface and bulk grain-oriented crystallization of stillwellite glasses for different conditions of synthesis of both planar surface (non-linear optic) and bulk (ferro/pyroclectric) textures based on oriented needle-shaped crystals of LaBGeO5 stillwellite. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1063 / 1067
页数:5
相关论文
共 16 条
[1]   Structural aspects of the 530 degrees C phase transition in LaBGeO5 [J].
Belokoneva, EL ;
David, WIF ;
Forsyth, JB ;
Knight, KS .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1997, 9 (17) :3503-3519
[2]  
Ding Y, 1998, PHYS CHEM GLASSES, V39, P338
[3]   Preparation of polar oriented Sr2TiSi2O8 films by surface crystallization of glass and second harmonic generation [J].
Ding, Y ;
Masuda, N ;
Miura, Y ;
Osaka, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 203 :88-95
[4]   ENHANCED SURFACE CRYSTALLIZATION OF BETA-BARIUM BORATE ON GLASS DUE TO ULTRASONIC TREATMENT [J].
DING, Y ;
OSAKA, A ;
MIURA, Y .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1994, 77 (03) :749-752
[5]   Optical non-linearity in oxide glasses [J].
Fargin, E ;
Berthereau, A ;
Cardinal, T ;
LeFlem, G ;
Ducasse, L ;
Canioni, L ;
Segonds, P ;
Sarger, L ;
Ducasse, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 203 :96-101
[6]  
HALLIYAL AG, 1989, GLASS GLASS CERAMICS, P272
[7]   2ND-HARMONIC GENERATION IN TRANSPARENT BARIUM BERATE GLASS-CERAMICS [J].
KAO, YH ;
HU, Y ;
ZHENG, HX ;
MACKENZIE, JD ;
PERRY, K ;
BOURHILL, G ;
PERRY, JW .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 167 (03) :247-254
[8]   2ND-ORDER AND 3RD-ORDER OPTICAL NONLINEARITY OF HOMOGENEOUS GLASSES [J].
NASU, H ;
MATSUOKA, J ;
KAMIYA, K .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 178 :23-30
[9]   OPTICAL-PROPERTIES OF TRANSPARENT GLASS-CERAMICS IN K2O-NB2O5-TEO2 GLASSES [J].
SHIOYA, K ;
KOMATSU, T ;
KIM, HG ;
SATO, R ;
MATUSITA, K .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 189 (1-2) :16-24
[10]   KTiOPO4 precipitation from potassium titanium phosphate glasses, producing second harmonic generation [J].
Sigaev, VN ;
Pernice, P ;
Aronne, A ;
Akimova, OV ;
Stefanovich, SY ;
Scaglione, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 292 (1-3) :59-69