Radical Polymer-Wrapped SWNTs at a Molecular Level: High-Rate Redox Mediation Through a Percolation Network for a Transparent Charge-Storage Material

被引：94

作者：

Choi, Wonsung ^{[1
,2
]}

Ohtani, Shota ^{[1
]}

Oyaizu, Kenichi ^{[1
]}

Nishide, Hiroyuki ^{[1
,2
]}

Geckeler, Kurt E. ^{[2
]}

机构：

[1] Waseda Univ, Dept Appl Chem, Tokyo 1698555, Japan

[2] GIST, Dept Nanobio Mat & Elect WCU, Kwangju 500712, South Korea

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 38期

关键词：

WALLED CARBON NANOTUBES; ACTIVE MATERIALS; BATTERY; FUNCTIONALIZATION;

D O I：

10.1002/adma.201102372

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A transparent nanocomposite of a radical polymer, the poly(2,2,6,6-tetramethylpiperidine-1-oxy-4-yl methacrylate) (PTMA), and single-walled carbon nanotubes (SWNTs) display a reversible charging and discharging, allowing full discharge in seconds. This is ascribed to the reversible electrochemical reaction of the pendant radical group in PTMA aided by both PTMA wrapping at a molecular level and the SWNT network for electrical conduction.

引用

收藏

页码：4440 / +

页数：5

相关论文

共 26 条

[1]

[Anonymous], 2010, ADV NANOMATERIALS

[2] Lithium Salt of Tetrahydroxybenzoquinone: Toward the Development of a Sustainable Li-Ion Battery [J].

Chen, Haiyan ;

Armand, Michel ;

Courty, Matthieu ;

Jiang, Meng ;

Grey, Clare P. ;

Dolhem, Franck ;

Tarascon, Jean-Marie ;

Poizot, Philippe .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8984-8988

[3] Coagulation method for preparing single-walled carbon nanotube/poly(methyl methacrylate) composites and their modulus, electrical conductivity, and thermal stability [J].

Du, FM ;

Fischer, JE ;

Winey, KI .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (24) :3333-3338

[4]

Geckeler KurtE., 2006, FUNCTIONAL NANOMATER

[5] Heck reaction on single-walled carbon nanotubes.: Synthesis and photochemical properties of a wall functionalized SWNT-anthracene derivative [J].

Jose Gomez-Escalonilla, Maria ;

Atienzar, Pedro ;

Garcia Fierro, Jose Luis ;

Garcia, Hermenegildo ;

Langa, Fernando .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (13) :1592-1600

[6] Individualization of single-walled carbon nanotubes: Is the solvent important? [J].

Kim, DS ;

Nepal, D ;

Geckeler, KE .

SMALL, 2005, 1 (11) :1117-1124

[7] Reduction-Controlled Viologen in Bisolvent as an Environmentally Stable n-Type Dopant for Carbon Nanotubes [J].

Kim, Soo Min ;

Jang, Jin Ho ;

Kim, Ki Kang ;

Park, Hyeon Ki ;

Bae, Jung Jun ;

Yu, Woo Jong ;

Lee, Il Ha ;

Kim, Gunn ;

Loc, Duong Dinh ;

Kim, Un Jeong ;

Lee, Eun-Hong ;

Shin, Hyeon-Jin ;

Choi, Jae-Young ;

Lee, Young Hee .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :327-331

[8] Organic Radical Battery Approaching Practical Use [J].

Nakahara, Kentaro ;

Oyaizu, Kenichi ;

Nishide, Hiroyuki .

CHEMISTRY LETTERS, 2011, 40 (03) :222-227

[9] A facile and rapid purification method for single-walled carbon nanotubes [J].

Nepal, D ;

Kim, DS ;

Geckeler, KE .

CARBON, 2005, 43 (03) :660-662

[10] Strong antimicrobial coatings: Single-walled carbon nanotubes armored with biopolymers [J].

Nepal, Dhriti ;

Balasubramanian, Shankar ;

Simonian, Aleksandr L. ;

Davis, Virginia A. .

NANO LETTERS, 2008, 8 (07) :1896-1901