Metal complexes as host molecules: The X-ray crystal structure of [Mo{HB(3,5-Me(2)pz)(3)}(NO){1,3-O-2-4-CH2(C6H13)C6H2}](4)center dot 2CH(2)Cl(2)

被引：8

作者：

Berridge, TE ^{[1
]}

Chen, HL ^{[1
]}

Hamor, TA ^{[1
]}

Jones, CJ ^{[1
]}

机构：

[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

来源：

POLYHEDRON | 1997年 / 16卷 / 13期

基金：

英国工程与自然科学研究理事会;

关键词：

molybdenum; nitrosyl; cyclophane; inclusion compound; hydrogen bond;

D O I：

10.1016/S0277-5387(96)00558-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [Mo(HBpz(3))(NO)I-2] and tetrahexylcalix[4]resorcinarene affords container molecules in which two, three or four {Mo(HBpz(3))(NO)} units are incorporated into the rim to produce a host site. A crystal structure of the tetrametallated derivative reveals that one nitrosyl ligand forms a hydrogen bond with a CH2Cl2 guest molecule included in the host site. (C) 1997 Elsevier Science Ltd.

引用

页码：2329 / 2333

页数：5

共 28 条

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