Design of a solid inclusion compound with optimal properties as a linear dichroic filter for X-ray polarization analysis

被引：27

作者：

Chao, MH

Kariuki, BM

Harris, KDM ^{[1
]}

Collins, SP

Laundy, D

机构：

[1] Univ Birmingham, Sch Chem Sci, Birmingham B15 2TT, W Midlands, England

[2] SERC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 26期

关键词：

host-guest systems; inclusion compounds; X-ray diffraction; X-ray polarization analysis;

D O I：

10.1002/anie.200350891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new molecular material - the 1-bromoadamantane/thiourea inclusion compound (the guest substructure of which is depicted) - has been designed as a dichroic filter for X-ray polarization analysis, based on theoretical predictions of the required structural characteristics. Measurements of X-ray linear dichroism show that this material exhibits essentially optimal performance in such applications.

引用

收藏

页码：2982 / 2985

页数：4

相关论文

共 16 条

[1] Structural and dynamic properties of the 1,10-dibromodecane/urea inclusion compound, investigated by variable-temperature powder X-ray diffraction, solid-state H-2 NMR lineshape analysis and solid-state H-2 NMR spin-lattice relaxation time measurements [J].

Aliev, AE ;

Smart, SP ;

Shannon, IJ ;

Harris, KDM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (12) :2179-2185

[2] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[3] ANGULAR-DEPENDENCE OF X-RAY ABSORPTION-SPECTRA [J].

BROUDER, C .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1990, 2 (03) :701-738

[4]

CHAO MH, UNPUB

[5] X-ray linear dichroism in an α,ω-dibromoalkane/urea inclusion compound and its application to polarization analysis of magnetic diffraction [J].

Collins, SP ;

Laundy, D ;

Harris, KDM ;

Kariuki, BM ;

Bauer, CL ;

Brown, SD ;

Thompson, P .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (01) :123-134

[6] SRS Station 16.3: description and utilization of a high-resolution diffraction facility [J].

Collins, SP ;

Murphy, BM ;

Tang, CC ;

Miller, MC ;

Oszlanyi, G .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1999, 32 (10A) :A81-A83

[7] POLARIZATION AND RESONANCE STUDIES OF X-RAY MAGNETIC SCATTERING IN HOLMIUM [J].

GIBBS, D ;

GRUBEL, G ;

HARSHMAN, DR ;

ISAACS, ED ;

MCWHAN, DB ;

MILLS, D ;

VETTIER, C .

PHYSICAL REVIEW B, 1991, 43 (07) :5663-5681

[8] ADAMANTANE INCLUSION COMPLEXES WITH THIOUREA AND SELENOUREA [J].

GOPAL, R ;

ROBERTSON, BE ;

RUTHERFORD, JS .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :257-259

[9] NEUTRON-SCATTERING INVESTIGATIONS OF GUEST MOLECULAR-DYNAMICS IN ALPHA, OMEGA-DIBROMOALKANE UREA INCLUSION-COMPOUNDS [J].

GUILLAUME, F ;

SMART, SP ;

HARRIS, KDM ;

DIANOUX, AJ .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1994, 6 (11) :2169-2184

[10] STRUCTURAL ASPECTS OF UREA INCLUSION-COMPOUNDS AND THEIR INVESTIGATION BY X-RAY-DIFFRACTION - A GENERAL DISCUSSION [J].

HARRIS, KDM ;

THOMAS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (17) :2985-2996